Hello augustl,
Welcome to the Maple. I think the next year will be very exciting, with the arrival of the new IDE and the new boards, and with new users who want to learn the details. Eventually, I may become more interested in this level of detail, but in the near future I will be more focused on contributing and testing new features (in particular DMA coupled to isochronous USB data transfers using double-buffers; I think that is possible).
Is there any guide from Arduino-land which has the right amount of "behind the scene" explanations which will make you happy? This might result in an improved answer from a user or at least a "that is something which we have on our to do list" answer from the leaflabs crew.
Of even better, one of the maple/arduino linux code sourcery gurus might be able to take an Arduino guide which you like and quickly translate it it into something for the Maple.
A few months ago there were some topics related to compiler optimizations settings. Is this the info which you want?
On a more practical note, I understand that you do not want to use the IDE. However, were you able to compile and upload any sketches using the unix-toolchain or the IDE? This will at least you that everything is installed in the expected places.
I have not tried to add content to the wiki, but I am looking forward to your contributions.
Good luck-
Stephen from NYC (full disclosure: I am not a member of the LeafLabs staff)