Those numbers for pin occupation are an overestimation. Since for a while now MII has been deprecated in favour of RMII. The correct choice going forward is RMII for any PHY data bus.
The 9 pins of RMII on the F107/207 are: 25, 26, 32, 48, 51, 52, 16, 33, 34,
+ shared connections which may / may not be non-exclusive. They are RESET, 25Mhz OSC. Wake on lan is not represented, might be covered by RMII bus. Note: Theres no different circuit for 10mbit. Thats acheived by doing 100mbit, for 1/10th of the time.
Lets be specific. Of the 9 pins occupied by RMII, the most significant conflicts are:
USART2 CTS,RTS,TX (23,24,25)
USART3 RX,CK,CTS (48,51,52),
CAN2 RX,TX (51,52),
SPI1 MOSI (32)
TIM1 CH1N (32)
These same pins (its true) are in addition also used by other timers and ADCs and can be looked up further.