dreamcat4 -
Its true that an F2 chip could work on a RET6 board, with only a slight modification.
Thanks for the clarification about modifying the board. I interpreted your previous comments as using an unmodified board. This is clearer.
According to the next page in the ST Manual it shows the 64 LQFP package has only one decoupling capacitor.
The datasheet for the STM32F205xx STM32F207xx:
http://www.st.com/internet/com/TECHNICAL_RESOURCES/TECHNICAL_LITERATURE/DATASHEET/CD00237391.pdf
in section 2.1 "Full compatibility throughout the family", Figure 3. "Compatible board design: LQFP64", shows TWO decoupling capacitors added to the 64pin LQFP STM32F20xxx, and two breaks in the Vss tracks.
The two pins, 31 and 47, change from Vss_1 and Vss_2 to Vcap_1 and Vcap_2 respectively.
The decoupling capacitors are inserted by breaking the direct connection from pin 31 and pin 47 to Vss, which is ground, not as becker says to +3V.
Most PCBs for processors which run at 20MHz+ have a 'copper pour' ground plane which is more difficult to modify than signal tracks.
On a 64 pin LQFP STM32F103, the neighbouring Vdd pins 32 and 48, are normally connected to pin 31 and 47 via a decoupling capacitor which are (recommended to be) very near to both Vdd & Vss pins.
My interpretation of section 5.1.6 "Power supply scheme" is those Vdd pins will still need to remain connected to their decoupling capacitors
So the modification needs to leave the existing (STM32F103) decouping capacitor connected to Vdd and the ground connection, so there isn't much room to manoeuvre.
On Maple Rev 5, pin 31 is connected to Vss (ground) using a via UNDER the chip, so the chip would need to be removed from the PCB to sever the track, or the via might be removed by very carefully drilling out (it isn't a blind via) but this can be tricky as a 'wisp' of copper may be left to short between layers. Pin 47 is a bit easier as the connection to Vss is a short visible track to a via.
Once the tracks are broken two new, extra, decoupling capacitors need to be connected to the pins and Vss (ground).
Having said all this, I am willing to believe that you are sufficiently skilled to be able to make the modifications. I don't count those as slight modifications on an assembled board, but maybe you do. I'll be interested to see how you do it.
I am posting this to ensure that other folks realise it is NOT likely to be straightforward on a PCB which is not designed to support the modification.
It would be relatively straightforward to design a PCB to take an STM32F20xxx, and make it backwardly compatible with an STM32F103xx. I might do that.